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期刊论文 10

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主-客体化学 1

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Generating native user interfaces formultiple devices by means ofmodel transformation

Ignacio MARIN,Francisco ORTIN,German PEDROSA,Javier RODRIGUEZ

《信息与电子工程前沿(英文)》 2015年 第16卷 第12期   页码 995-1017 doi: 10.1631/FITEE.1500083

摘要: In the last years, the types of devices used to access information systems have notably increased using different operating systems, screen sizes, interaction mechanisms, and software features. This device fragmentation is an important issue to tackle when developing native mobile service front-end applications. To address this issue, we propose the generation of native user interfaces (UIs) by means of model transformations, following the modelbased user interface (MBUI) paradigm. The resulting MBUI framework, called LIZARD, generates applications for multiple target platforms. LIZARD allows the definition of applications at a high level of abstraction, and applies model transformations to generate the target native UI considering the specific features of target platforms. The generated applications follow the UI design guidelines and the architectural and design patterns specified by the corresponding operating system manufacturer. The objective is not to generate generic applications following the lowest-common-denominator approach, but to follow the particular guidelines specified for each target device. We present an example application modeled in LIZARD, generating different UIs for Windows Phone and two types of Android devices (smartphones and tablets).

关键词: Model-to-model transformation     Native user interfaces     Model-based user interfaces     Model-driven engineering    

聚焦两相界面

沈平

《工程(英文)》 2021年 第7卷 第5期   页码 552-553 doi: 10.1016/j.eng.2021.02.003

Two-dimensional self-assembly of melem and melemium cations at pH-controlled aqueous solution–Au(111) interfaces

Shinobu Uemura,Kenki Sakata,Masashi Aono,Yusuke Nakamura,Masashi Kunitake

《化学科学与工程前沿(英文)》 2016年 第10卷 第2期   页码 294-300 doi: 10.1007/s11705-016-1564-4

摘要: Two-dimensional self-assembly of melem at pH-controlled aqueous solution-Au(111) interfaces has been investigated by electrochemical scanning tunneling microscopy. In the solutions with pH>p of melem, two ordered self-assembled structures (honeycomb and close-packed structures) and one disordered fibrillar structure were observed as a function of the surface coverage of melem controlled by the electrode potential. In contrast, in the acidic solution with pH

关键词: self-assembly     scanning tunneling microscopy     electrochemistry     structural phase transition     melem    

Gas marbles: ultra-long-lasting and ultra-robust bubbles formed by particle stabilization

《化学科学与工程前沿(英文)》   页码 1681-1687 doi: 10.1007/s11705-022-2180-0

摘要: Bubbles and foams are ubiquitous in daily life and industrial processes. Studying their dynamic behaviors is of key importance for foam manufacturing processes in food packaging, cosmetics and pharmaceuticals. Bare bubbles are inherently fragile and transient; enhancing their robustness and shelf lives is an ongoing challenge. Their rupture can be attributed to liquid evaporation, thin film drainage and the nuclei of environmental dust. Inspired by particle-stabilized interfaces in Pickering emulsions, armored bubbles and liquid marble, bubbles are protected by an enclosed particle-entrapping liquid thin film, and the resultant soft object is termed gas marble. The gas marble exhibits mechanical strength orders of magnitude higher than that of soap bubbles when subjected to overpressure and underpressure, owing to the compact particle monolayer straddling the surface liquid film. By using a water-absorbent glycerol solution, the resulting gas marble can persist for 465 d in normal atmospheric settings. This particle-stabilizing approach not only has practical implications for foam manufacturing processes but also can inspire the new design and fabrication of functional biomaterials and biomedicines.

关键词: bubble     particles     interfaces     armored bubble     liquid marble     gas marble     Pickering emulsion    

Controlling microbiological interfacial behaviors of hydrophobic organic compounds by surfactants in biodegradation process

ZHANG Dong,ZHU Lizhong

《环境科学与工程前沿(英文)》 2014年 第8卷 第3期   页码 305-315 doi: 10.1007/s11783-014-0647-z

摘要: Bioremediation of hydrophobic organic compounds (HOCs) contaminated soils involves several physicochemical and microbiological interfacial processes among the soil-water-microorganism interfaces. The participation of surfactants facilitates the mass transport of HOCs in both the physicochemical and microbiological interfaces by reducing the interfacial tension. The effects and underlying mechanisms of surfactants on the physicochemical desorption of soil-sorbed HOCs have been widely studied. This paper reviewed the progress made in understanding the effects of surfactant on microbiological interfacial transport of HOCs and the underlying mechanisms, which is vital for a better understanding and control of the mass transfer of HOCs in the biodegradation process. In summary, surfactants affect the microbiological interfacial behaviors of HOCs during three consecutive processes: the soil solution-microorganism sorption, the transmembrane process, and the intracellular metabolism. Surfactant could promote cell sorption of HOCs depending on the compatibility of surfactant hydrophile hydrophilic balance (HLB) with cell surface properties; while the dose ratio between surfactant and biologic mass (membrane lipids) determined the transmembrane processes. Although surfactants cannot easily directly affect the intracellular enzymatic metabolism of HOCs due to the steric hindrace, the presence of surfactants can indirectly enhanced the metabolism by increasing the substrate concentrations.

关键词: biodegradation     sorption     transmembrane transport     microbiological interfaces     surfactants    

Effects of preparation methods on the activity of CuO/CeO

Huanhuan Shang, Xiaoman Zhang, Jing Xu, Yifan Han

《化学科学与工程前沿(英文)》 2017年 第11卷 第4期   页码 603-612 doi: 10.1007/s11705-017-1661-z

摘要: CO oxidation has been investigated on three CuO/CeO catalysts prepared by impregnation, co-precipitation and mechanical mixing. The origin of active sites was explored by the multiple techniques. The catalyst prepared by impregnation has more highly dispersed CuO and stronger interactions between CuO and CeO to promote the reduction of CuO to Cu species at the Cu-Ce interface, leading to its highest catalytic activity. For the catalyst prepared by co-precipitation, solid solution structures observed in Raman spectra suppress the formation of the Cu-Ce interface, where the adsorbed CO will react with active lattice oxygen to form CO , and thus it displays a lower catalytic performance. No Cu-Ce interface exists in the catalyst prepared by the mechanical mixing method due to the separate phases of CuO and CeO , resulting in its lowest activity among the three catalysts.

关键词: CuO/CeO2     CO oxidation     interfaces     structure-performance relationship     active sites    

Influence of surface modified mixed metal oxide nanoparticles on the electrochemical and mechanical properties of polyurethane matrix

《化学科学与工程前沿(英文)》 2023年 第17卷 第1期   页码 1-14 doi: 10.1007/s11705-022-2176-9

摘要: Newly synthesized functional nanoparticles, 3-amino-1,2,4-triazole (ATA)/SiO2–TiO2 were introduced to the polyurethane (PU) matrix. Electrochemical techniques were used to investigate the barrier properties of the synthesized PU–ATA/SiO2–TiO2 nanocomposite coated steel specimen. In natural seawater, electrochemical impedance spectroscopy experiments indicated outstanding protective behaviour for the PU–ATA/SiO2–TiO2 coated steel. The coating resistance (Rcoat) of PU–ATA/SiO2–TiO2 was determined to be 2956.90 kΩ·cm–2. The Rcoat of the PU–ATA/SiO2–TiO2 nanocomposite coating was found to be over 50% higher than the PU coating. The current measured along the scratched surface of the PU–ATA/SiO2–TiO2 coating was found to be very low (1.65 nA). The enhanced ATA/SiO2–TiO2 nanoparticles inhibited the entry of electrolytes into the coating interface, as revealed by scanning electron microscopy/energy dispersive X-ray spectroscopy and X-ray diffraction analysis of the degradation products. Water contact angle testing validated the hydrophobic nature of the PU–ATA/SiO2–TiO2 coating (θ = 115.4°). When the concentration of ATA/SiO2−TiO2 nanoparticles was 2 wt %, dynamic mechanical analysis revealed better mechanical properties. Therefore, the newly synthesised PU–ATA/SiO2–TiO2 nanocomposite provided excellent barrier and mechanical properties due to the addition of ATA/SiO2–TiO2 nanoparticles to the polyurethane, which inhibited material degradation and aided in the prolongation of the coated steel’s life.

关键词: SiO2/TiO2 nanoparticle     nanocomposite coatings     dynamic mechanical analysis     electrochemical techniques     corrosion     colloids and interfaces    

Recent development and application of thin-film thermoelectric cooler

Yuedong Yu, Wei Zhu, Xixia Kong, Yaling Wang, Pengcheng Zhu, Yuan Deng

《化学科学与工程前沿(英文)》 2020年 第14卷 第4期   页码 492-503 doi: 10.1007/s11705-019-1829-9

摘要: Recently, the performance and fabrication of thin-film thermoelectric materials have been largely enhanced. Based on this enhancement, the thin-film thermoelectric cooler (TEC) is becoming a research hot topic, due to its high cooling flux and microchip level size. To fulfill a thin-film TEC, interfacial problems are unavoidable, as they may largely reduce the properties of a thin-film TEC. Moreover, the architecture of a thin-film TEC should also be properly designed. In this review, we introduced the enhancement of thermoelectric properties of (Bi,Sb) (Te,Se) solid solution materials by chemical vapor deposition, physical vapor deposition and electrodeposition. Then, the interfacial problems, including contact resistance, interfacial diffusion and thermal contact resistance, were discussed. Furthermore, the design, fabrication, as well as the performance of thin-film TECs were summarized.

关键词: thin-film thermoelectric cooler     interfaces     cooling flux     TE device fabrication    

基于脑电图的脑-机接口系统在实用化进程中面临的挑战

许敏鹏, 何峰, 钟子平, 顾晓松, 明东

《工程(英文)》 2021年 第7卷 第12期   页码 1710-1712 doi: 10.1016/j.eng.2021.09.011

基于液-液界面的主-客体分子识别 Review

王贝贝, 陈浩, 刘倓, 史少伟, Thomas P. Russell

《工程(英文)》 2021年 第7卷 第5期   页码 603-614 doi: 10.1016/j.eng.2021.02.004

摘要:

由于动态和可逆的性质,主-客体识别作为一种非共价键相互作用,赋予了液-液界面独特的性质,包括刺激响应性和自调节性等。近年来,越来越多的研究致力于通过在液-液界面上集成功能性单元(如胶体粒子、聚合物)来构筑二维薄膜和微胶囊等超分子界面体系,这为物质封装、递送、双相反应器等领域提供了重要的发展机遇。在本文中,我们总结了近年来基于主-客体相互作用构筑超分子界面体系的研究进展,并对其制备方法、功能和应用进行了概述。

关键词: 液-液界面     自组装     主-客体化学     微胶囊    

标题 作者 时间 类型 操作

Generating native user interfaces formultiple devices by means ofmodel transformation

Ignacio MARIN,Francisco ORTIN,German PEDROSA,Javier RODRIGUEZ

期刊论文

聚焦两相界面

沈平

期刊论文

Two-dimensional self-assembly of melem and melemium cations at pH-controlled aqueous solution–Au(111) interfaces

Shinobu Uemura,Kenki Sakata,Masashi Aono,Yusuke Nakamura,Masashi Kunitake

期刊论文

Gas marbles: ultra-long-lasting and ultra-robust bubbles formed by particle stabilization

期刊论文

Controlling microbiological interfacial behaviors of hydrophobic organic compounds by surfactants in biodegradation process

ZHANG Dong,ZHU Lizhong

期刊论文

Effects of preparation methods on the activity of CuO/CeO

Huanhuan Shang, Xiaoman Zhang, Jing Xu, Yifan Han

期刊论文

Influence of surface modified mixed metal oxide nanoparticles on the electrochemical and mechanical properties of polyurethane matrix

期刊论文

Recent development and application of thin-film thermoelectric cooler

Yuedong Yu, Wei Zhu, Xixia Kong, Yaling Wang, Pengcheng Zhu, Yuan Deng

期刊论文

基于脑电图的脑-机接口系统在实用化进程中面临的挑战

许敏鹏, 何峰, 钟子平, 顾晓松, 明东

期刊论文

基于液-液界面的主-客体分子识别

王贝贝, 陈浩, 刘倓, 史少伟, Thomas P. Russell

期刊论文